JEE Chemistry
JEEChemistryHydrocarbonsClass 11

I keep getting “Markovnikov's rule” questions wrong in Hydrocarbons. What's the trap?

reversing it, except in the peroxide (anti-Markovnikov) effect.

The usual trap: reversing it, except in the peroxide (anti-Markovnikov) effect. How to avoid it: 'the rich get richer' — the H-rich carbon gains the H. Go back to the definition — when HX adds to an alkene, H attaches to the carbon that already has more hydrogens.

Key point

Markovnikov's rule

Common mistake

reversing it, except in the peroxide (anti-Markovnikov) effect.

Memory tip

'the rich get richer' — the H-rich carbon gains the H.

Tap to watch or see it right here — the app stays open (it only opens a quick search if nothing embeddable is found).

More on Hydrocarbons