JEE Chemistry
JEEChemistryHaloalkanes & HaloarenesClass 12

What is the difference between haloalkane and haloarene?

A haloalkane has halogen on an sp³ carbon and readily undergoes substitution; a haloarene has halogen on an aromatic ring where resonance and the sp² C–X bond make substitution much harder.

A haloalkane has halogen on an sp³ carbon and readily undergoes substitution; a haloarene has halogen on an aromatic ring where resonance and the sp² C–X bond make substitution much harder. A reliable way to keep them apart is to focus on what each one is defined by, not just the similar-sounding words.

Key point

haloalkane vs haloarene

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