JEE Chemistry
JEEChemistrySolutions & Colligative PropertiesClass 12

What does “van't Hoff factor (i)” actually mean in Solutions & Colligative Properties, and why does it matter for JEE?

the number of particles one formula unit gives in solution — about 2 for NaCl, 3 for CaCl₂, 1 for glucose.

In simple words: the number of particles one formula unit gives in solution — about 2 for NaCl, 3 for CaCl₂, 1 for glucose. Getting van't Hoff factor (i) clear matters because JEE questions on Solutions & Colligative Properties usually test this idea directly, not just a formula you memorised.

Key point

van't Hoff factor (i)

Common mistake

ignoring dissociation, so predicting equal effects for salt and sugar.

Memory tip

multiply the colligative effect by i for anything that dissociates.

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