NEET Chemistry
NEETChemistryAmines & BiomoleculesClass 12

How are diazonium salts used to make the bright dyes in clothes?

A primary aromatic amine treated with nitrous acid at low temperature (0–5°C) forms a diazonium salt.

A primary aromatic amine treated with nitrous acid at low temperature (0–5°C) forms a diazonium salt. This reactive intermediate couples with electron-rich aromatics (like phenols or amines) to form azo compounds, which contain the –N=N– group. The extended conjugation of azo dyes absorbs visible light strongly, giving the vivid, fast colours used in textiles.

Key point

Diazonium salts couple with aromatics to form coloured azo (–N=N–) dyes.

Common mistake

thinking diazonium salts are stable at room temperature.

Memory tip

keep diazonium cold (0–5°C), then couple it to make azo dyes.

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