NEET Chemistry
NEETChemistryHaloalkanes & HaloarenesClass 12

Why does a tertiary halide give a racemic (mixed left/right) product while a primary one gives a single mirror image?

A tertiary halide reacts by SN1 through a flat, planar carbocation.

A tertiary halide reacts by SN1 through a flat, planar carbocation. The nucleophile can then attack from either face with equal ease, so you get both mirror-image products — a racemic mixture. A primary halide reacts by SN2: the nucleophile attacks from directly behind the leaving group, flipping the centre like an umbrella (inversion), so you get one specific configuration.

Key point

SN1 (planar carbocation) racemises; SN2 (backside attack) inverts the configuration.

Common mistake

expecting both mechanisms to preserve the original geometry.

Memory tip

flat carbocation → attack from both sides → racemic; SN2 → clean inversion.

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