NEET Chemistry
NEETChemistryCoordination CompoundsClass 12

I keep getting “Ligands & coordination number” questions wrong in Coordination Compounds. What's the trap?

counting ligand molecules instead of donor atoms (a bidentate ligand donates twice).

The usual trap: counting ligand molecules instead of donor atoms (a bidentate ligand donates twice). How to avoid it: count donor atoms, not molecules, for the coordination number. Go back to the definition — ligands are electron-pair donors bonded to a central metal ion; the coordination number is how many donor atoms attach to it.

Key point

Ligands & coordination number

Common mistake

counting ligand molecules instead of donor atoms (a bidentate ligand donates twice).

Memory tip

count donor atoms, not molecules, for the coordination number.

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