The work function (W0) of a metal is the minimum energy required to just remove an electron from the surface of the metal without giving it any kinetic energy. The threshold frequency (f0) is the minimum frequency of the incident light below which no photoelectric emission takes place, however intense the light may be. They are related by W0 = h f0, where h is Planck's constant.

W0 = h f0

(1) For a given metal, photoelectric emission occurs only if the frequency of the incident light is greater than a certain minimum value (threshold frequency), whatever the intensity. (2) The maximum kinetic energy of the emitted photoelectrons depends on the frequency of the incident light and the nature of the metal, but is independent of the intensity of the light. (3) The number of photoelectrons emitted per second (photoelectric current) is directly proportional to the intensity of the incident light. (4) The emission is instantaneous, with no measurable time lag.

The de Broglie hypothesis states that every moving particle has a wave associated with it, called a matter wave. The de Broglie wavelength is lambda = h/p = h/(m v), where h is Planck's constant, p is the momentum, m is the mass and v the velocity of the particle. In terms of kinetic energy, lambda = h/sqrt(2 m KE). This shows the dual (wave-particle) nature of matter; the wavelength is significant only for very small particles like electrons.

lambda = h/(m v)