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The questions your board exam loves to ask

800 most-asked Class 11 & 12 (+1 / +2) questions across Physics, Chemistry, Maths and Biology — each with a model answer and the exact marking-scheme points examiners reward. Revise smart, walk in calm.

800 board questions•Model answers•Marking-scheme points•Every chapter•CBSE · ISC · State boards

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ChemistryClass 112 marksmedium

Organic Chemistry: Some Basic Principles and Techniques

What is the inductive effect? Distinguish between +I and -I effects.

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The inductive effect is the permanent displacement of the shared sigma-bond electron pair towards the more electronegative atom, transmitted through a chain of carbon atoms and decreasing with distance. Groups that push electrons away from themselves (electron-releasing, e.g. alkyl groups -CH3) show the +I effect, while groups that pull electrons towards themselves (electron-withdrawing, e.g. -NO2, -Cl) show the -I effect.

Marking-scheme points

  • ✓Permanent shift of sigma electrons due to electronegativity difference
  • ✓Transmitted through the chain, weakens with distance
  • ✓+I: electron releasing (alkyl); -I: electron withdrawing (-NO2, -Cl)
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ChemistryClass 112 marksmedium

Organic Chemistry: Some Basic Principles and Techniques

What is resonance? What is resonance energy? Give one example.

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Resonance is the representation of a molecule or ion by two or more structures (canonical/contributing structures) that differ only in the position of electrons, none of which alone describes it fully; the actual structure is a resonance hybrid. Resonance energy is the difference in energy between the resonance hybrid and the most stable contributing structure; the greater the resonance energy, the more stable the molecule. Example: benzene, which is a hybrid of two Kekule structures and is more stable than expected.

Marking-scheme points

  • ✓Molecule described by several canonical structures; real one is the hybrid
  • ✓Resonance energy = extra stability of hybrid over best single structure
  • ✓Example: benzene (Kekule structures), carbonate ion
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ChemistryClass 112 markseasy

Organic Chemistry: Some Basic Principles and Techniques

Define electrophile and nucleophile with two examples each.

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An electrophile (electron-loving) is an electron-deficient species that accepts a pair of electrons; examples: H+, NO2+ (also positively charged or neutral electron-deficient species like BF3). A nucleophile (nucleus-loving) is an electron-rich species that donates a pair of electrons; examples: OH-, CN- (also neutral species with lone pairs like NH3 and H2O).

Marking-scheme points

  • ✓Electrophile: electron-deficient, accepts electron pair (H+, NO2+)
  • ✓Nucleophile: electron-rich, donates electron pair (OH-, CN-)
  • ✓Electrophiles are Lewis acids; nucleophiles are Lewis bases
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