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The questions your board exam loves to ask

800 most-asked Class 11 & 12 (+1 / +2) questions across Physics, Chemistry, Maths and Biology — each with a model answer and the exact marking-scheme points examiners reward. Revise smart, walk in calm.

800 board questions•Model answers•Marking-scheme points•Every chapter•CBSE · ISC · State boards

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ChemistryClass 113 marksmedium

Classification of Elements and Periodicity

How does atomic radius vary across a period and down a group? Give reasons.

Reveal model answer + marking points▾

Across a period (left to right), atomic radius decreases because nuclear charge increases while electrons are added to the same shell, so the increased effective nuclear charge pulls the electron cloud closer. Down a group, atomic radius increases because a new shell is added at each step and the number of inner shielding electrons increases, outweighing the rise in nuclear charge.

Marking-scheme points

  • ✓Across period: radius decreases (rising effective nuclear charge, same shell)
  • ✓Down group: radius increases (new shells added)
  • ✓Shielding by inner electrons increases down a group
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ChemistryClass 112 marksmedium

Classification of Elements and Periodicity

Why is the first ionization enthalpy of nitrogen greater than that of oxygen?

Reveal model answer + marking points▾

Nitrogen has the configuration 1s2 2s2 2p3 with a half-filled 2p subshell, which is extra stable due to symmetry and exchange energy, so removing an electron requires more energy. Oxygen (1s2 2s2 2p4) has one paired electron in 2p; removing it relieves electron-electron repulsion and gives a stable half-filled configuration, so less energy is needed. Hence IE1 of nitrogen > oxygen.

Marking-scheme points

  • ✓N has stable half-filled 2p3 configuration
  • ✓O 2p4 has electron-pair repulsion, easier to remove
  • ✓So IE1(N) > IE1(O)
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ChemistryClass 113 marksmedium

Classification of Elements and Periodicity

Define ionization enthalpy. Explain its trend across a period and down a group.

Reveal model answer + marking points▾

Ionization enthalpy is the minimum energy required to remove the most loosely bound electron from an isolated gaseous atom in its ground state. Across a period it increases because nuclear charge increases and atomic size decreases, so the electron is held more tightly. Down a group it decreases because atomic size increases and shielding by inner electrons increases, so the outer electron is more easily removed.

M(g) -> M+(g) + e-

Marking-scheme points

  • ✓Energy to remove electron from gaseous atom
  • ✓Increases across a period (size down, nuclear charge up)
  • ✓Decreases down a group (size and shielding up)
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