Fundamentals

1,200 must-knows for NEET & JEE

The core facts every aspirant should own — each a titled nugget with a real-world story, the concept in plain words, and a memory trick. Works even when the internet doesn't.

1,200 fundamentals

ChemistryRedox Reactions· Class 11

Oxidation number rules

A quick bookkeeping system for tracking electron transfer.

Free elements are 0, oxygen is usually −2, hydrogen +1, and the sum equals the ion's charge.

Memory trick: Sum = overall charge.

ChemistrySome Basic Concepts (Mole Concept)· Class 11

Percentage yield

Real reactions rarely give 100% — side reactions and losses eat into the total.

Actual yield divided by theoretical yield, times 100.

Memory trick: Real ÷ theoretical × 100.

ChemistrySolutions· Class 12

Concentration: ppm

Safe drinking-water limits for metals are quoted in ppm.

Parts per million expresses very dilute concentrations.

Memory trick: 1 ppm = 1 mg per litre.

ChemistrySome Basic Concepts (Mole Concept)· Class 11

Law of conservation of mass

Whatever mass goes into a sealed reaction comes back out.

Mass is neither created nor destroyed in a chemical reaction.

Memory trick: Reactant mass = product mass.

ChemistrySome Basic Concepts (Mole Concept)· Class 11

Law of definite proportions

Water is always 8:1 oxygen to hydrogen by mass, from any source.

A pure compound always contains its elements in the same fixed mass ratio.

Memory trick: Fixed ratio, always.

ChemistrySome Basic Concepts (Mole Concept)· Class 11

Accuracy vs precision

A dartboard can be precise but off-target — tight but inaccurate.

Accuracy is closeness to the true value; precision is repeatability.

Memory trick: Close vs consistent.

ChemistrySome Basic Concepts (Mole Concept)· Class 11

Stoichiometry

It's the recipe maths of chemistry — how much yields how much.

Using balanced equations to relate amounts of reactants and products.

Memory trick: Balance first, then ratio.

ChemistrySolutions· Class 12

Osmosis

Plant roots drink water by osmosis, and it's why salted slugs shrivel.

Solvent flows through a semipermeable membrane from dilute to concentrated.

Memory trick: Solvent moves to the saltier side.

ChemistrySolutions· Class 12

Osmotic pressure

Reverse osmosis purifies seawater by overpowering this pressure.

The pressure needed to stop osmosis; a colligative property.

π = CRT

Memory trick: Depends on particle count.

ChemistrySolutions· Class 12

Van't Hoff factor

One mole of NaCl gives two particles, doubling its colligative effect.

Accounts for particles formed when a solute dissociates or associates.

Memory trick: Counts actual particles.

ChemistryElectrochemistry· Class 12

Molar conductivity

Spread ions farther apart and each carries current more freely.

Conductivity per mole of electrolyte; it rises on dilution.

Memory trick: Increases with dilution.

ChemistryElectrochemistry· Class 12

Standard hydrogen electrode

Every electrode potential is measured against this agreed zero.

The reference electrode assigned a potential of exactly zero volts.

Memory trick: Reference = 0 V.

ChemistryChemical Kinetics· Class 12

Collision theory

Most collisions bounce off harmlessly; only the right ones react.

Reactions occur when particles collide with enough energy and correct orientation.

Memory trick: Energy + orientation.

ChemistryChemical Kinetics· Class 12

Pseudo first-order reaction

Sugar hydrolysis looks first-order because water is overwhelmingly abundant.

A higher-order reaction that behaves as first-order because one reactant is in large excess.

Memory trick: Excess reactant hides its order.

ChemistryChemical Kinetics· Class 12

Rate-determining step

A reaction is only as fast as its slowest bottleneck.

The slowest step in a mechanism sets the overall reaction rate.

Memory trick: Slowest step rules the rate.

ChemistryStates of Matter· Class 11

Critical temperature

You can't squeeze oxygen into liquid at room temperature — you must cool it first.

Above it, a gas cannot be liquefied by pressure alone.

Memory trick: Above it, no liquefaction.

ChemistryChemical Bonding & Molecular Structure· Class 11

Formal charge

It helps pick which Lewis structure nature actually prefers.

Bookkeeping charge on an atom in a Lewis structure, guiding the best structure.

Memory trick: Lowest formal charges win.

ChemistryChemical Bonding & Molecular Structure· Class 11

Fajans' rules

They explain why some 'ionic' compounds behave partly covalent.

Small, highly charged ions give bonds more covalent character.

Memory trick: Small + high charge → covalent.

ChemistryChemical Bonding & Molecular Structure· Class 11

Molecular orbital theory: O₂ is paramagnetic

The theory that finally explained why oxygen sticks to a magnet.

MOT correctly predicts O₂ has two unpaired electrons, so liquid oxygen is attracted to a magnet.

Memory trick: O₂ has unpaired electrons.

ChemistryOrganic Chemistry — Basic Concepts· Class 11

Hyperconjugation

The 'no-bond resonance' that steadies carbocations and alkenes.

Stabilisation from overlap of a σ-bond with an adjacent empty or partly filled orbital.

Memory trick: σ-electrons lend stability.

ChemistryOrganic Chemistry — Basic Concepts· Class 12

Chirality

One mirror-form of a drug can heal while the other harms.

A molecule that can't be superimposed on its mirror image is chiral, like your hands.

Memory trick: Non-superimposable mirror images.

ChemistryAldehydes, Ketones & Carboxylic Acids· Class 12

Tautomerism

Keto and enol forms flip back and forth in many carbonyl compounds.

A molecule rapidly interconverts between structural isomers, usually by shifting an H.

Memory trick: H hops between two forms.

ChemistryThe p-Block Elements· Class 12

Haber process

This reaction feeds roughly half the world's population.

N₂ + 3H₂ ⇌ 2NH₃ over an iron catalyst makes ammonia for fertilisers.

N₂+3H₂⇌2NH₃

Memory trick: Iron catalyst, high pressure.

ChemistryThe p-Block Elements· Class 12

Contact process

Sulphuric acid is the most-produced industrial chemical on Earth.

Industrial sulphuric acid is made by oxidising SO₂ to SO₃ over a V₂O₅ catalyst.

Memory trick: V₂O₅ catalyst.

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