Ostwald process
“It turns ammonia into the acid behind fertilisers and explosives.”
Nitric acid is made by catalytically oxidising ammonia.
Memory trick: NH₃ → HNO₃.
Fundamentals
The core facts every aspirant should own — each a titled nugget with a real-world story, the concept in plain words, and a memory trick. Works even when the internet doesn't.
1,200 fundamentals
“It turns ammonia into the acid behind fertilisers and explosives.”
Nitric acid is made by catalytically oxidising ammonia.
Memory trick: NH₃ → HNO₃.
“It fizzes on a cut as it releases oxygen.”
A pale blue liquid, a strong oxidiser used as a bleach and antiseptic.
H₂O₂
Memory trick: Oxidiser and bleach.
“Hard water leaves scum and scales up kettles.”
Hard water contains Ca²⁺/Mg²⁺ ions that stop soap from lathering.
Memory trick: Ca/Mg ions = hardness.
“Mixing halogens makes fiercely reactive hybrids.”
Compounds between two different halogens (e.g. ICl), generally more reactive than the parent halogens.
Memory trick: Halogen + halogen.
“The exact split decides whether a gemstone glows red or green.”
Ligands split a metal's d-orbitals in energy, explaining complex colour and magnetism.
Memory trick: Ligands split the d-orbitals.
“Strong-field ligands can force electrons to pair up.”
Ligands ranked by how strongly they split d-orbitals.
Memory trick: Strong vs weak field ligands.
“Cisplatin fights cancer, but its trans isomer doesn't — shape is everything.”
Coordination compounds show geometrical, optical and linkage isomerism.
Memory trick: Same formula, different arrangement.
“A chemist's power tool for stitching carbon skeletons together.”
R–MgX reacts with carbonyls to build new carbon–carbon bonds.
Memory trick: Adds R to C=O.
“It's a molecular knife that shows exactly where the double bond sat.”
Ozone cleaves a C=C double bond, revealing where it was located.
Memory trick: Cuts at the C=C.
“A gleaming silver coating on the tube flags an aldehyde.”
Aldehydes reduce Tollens' reagent to deposit a silver mirror; ketones don't.
Memory trick: Silver mirror = aldehyde.
“A yellow crystal and antiseptic smell reveal a CH₃CO group.”
Methyl ketones and ethanol give a yellow iodoform precipitate.
Memory trick: Yellow ppt → CH₃CO group.
“Le Chatelier turns a reversible reaction into a productive one.”
Acid + alcohol ⇌ ester + water; removing water drives it forward.
Memory trick: Remove water → more ester.
“Chlorine in water both gains and loses electrons at once.”
A single species is simultaneously oxidised and reduced.
Memory trick: Self oxidation + reduction.
“It's the reference book from which reaction enthalpies are computed.”
The enthalpy change when one mole of a compound forms from its elements in standard states.
Memory trick: Elements → 1 mole compound.
“Ice melts spontaneously above 0°C but not below — temperature tips ΔG.”
Whether a reaction is spontaneous can flip with temperature, since ΔG = ΔH − TΔS.
Memory trick: T can flip spontaneity.
“Copper wires are refined to 99.99% purity this way.”
Impure metal is purified by electrolysis, depositing pure metal on the cathode.
Memory trick: Pure metal plates the cathode.
“Goodyear's accidental discovery gave us durable car tyres.”
Heating rubber with sulphur cross-links the chains, making it tough and elastic.
Memory trick: Sulphur cross-links rubber.
“Green plastics that rot away instead of choking landfills.”
Polymers like PHBV break down naturally, easing plastic pollution.
Memory trick: Break down naturally.
“Dettol on a cut is antiseptic; floor cleaner is disinfectant.”
Antiseptics are safe on living tissue; disinfectants are for inanimate surfaces.
Memory trick: Skin-safe vs surface-only.
“They trick the tongue without feeding the waistline.”
Compounds like aspartame sweeten food with negligible calories.
Memory trick: Sweet taste, few calories.
“They quietly extend the shelf life of your pantry.”
Substances like sodium benzoate slow microbial spoilage of food.
Memory trick: Slow spoilage.
“Aspirin also thins blood, protecting hearts.”
Painkillers such as aspirin and paracetamol relieve pain.
Memory trick: Relieve pain.
“Count any gas by volume — 22.4 L is one mole of it.”
One mole of any ideal gas occupies 22.4 L at STP (0°C, 1 atm).
22.4 L/mol
Memory trick: 22.4 L per mole at STP.
“It's the exchange rate between moles of electrons and coulombs.”
The charge carried by one mole of electrons, about 96500 C.
F ≈ 96500 C
Memory trick: ~96500 C per mole e⁻.