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800 most-asked Class 11 & 12 (+1 / +2) questions across Physics, Chemistry, Maths and Biology — each with a model answer and the exact marking-scheme points examiners reward. Revise smart, walk in calm.
ChemistryClass 122 markseasy
Solutions
Define molarity, molality and mole fraction.
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Molarity (M) is the number of moles of solute per litre of solution (mol/L). Molality (m) is the number of moles of solute per kilogram of solvent (mol/kg); it is independent of temperature. Mole fraction of a component is the ratio of the number of moles of that component to the total number of moles of all components in the solution; it is dimensionless and the sum of the mole fractions equals 1.
M = n/V(L); m = n/mass of solvent(kg)
Marking-scheme points
- ✓Molarity = moles of solute/litre of solution (mol/L)
- ✓Molality = moles of solute/kg of solvent (mol/kg), temperature independent
- ✓Mole fraction = moles of component/total moles (dimensionless)
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Solutions
Calculate the molality of a solution containing 18 g of glucose (molar mass 180 g/mol) dissolved in 500 g of water.
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Moles of glucose = mass/molar mass = 18/180 = 0.1 mol. Mass of solvent (water) = 500 g = 0.5 kg. Molality = moles of solute/mass of solvent in kg = 0.1/0.5 = 0.2 mol/kg (0.2 m).
molality = moles of solute/mass of solvent (kg)
Marking-scheme points
- ✓Moles of glucose = 18/180 = 0.1 mol
- ✓Mass of water = 0.5 kg
- ✓Molality = 0.1/0.5 = 0.2 m
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Solutions
State Henry's law. Give one application.
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Henry's law states that at a constant temperature, the solubility of a gas in a liquid is directly proportional to the partial pressure of the gas over the liquid. Mathematically, p = KH x (mole fraction of gas), where KH is Henry's law constant. Applications: it explains why soft drinks (aerated under high pressure) fizz when opened, and why deep-sea divers can suffer from bends (nitrogen dissolving in blood under high pressure).
p = KH x (mole fraction)
Marking-scheme points
- ✓Solubility of a gas is proportional to its partial pressure
- ✓p = KH x (mole fraction of gas)
- ✓Application: aerated drinks, deep-sea diving (bends)
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Solutions
State Raoult's law for a solution of two volatile liquids.
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Solutions
What is the Van't Hoff factor? What does its value indicate for association and dissociation?
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Solutions
Distinguish between ideal and non-ideal solutions.
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Electrochemistry
What is a galvanic (voltaic) cell? Name its two electrodes and the reaction at each.
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Electrochemistry
What is standard electrode potential? What is taken as the reference electrode?
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Electrochemistry
Write the relation between the standard Gibbs energy change and the EMF of a cell.
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Electrochemistry
State Faraday's two laws of electrolysis.
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Electrochemistry
A current of 5 A is passed through a silver nitrate solution for 30 minutes. Calculate the mass of silver deposited. (Atomic mass of Ag = 108, F = 96500 C/mol)
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Electrochemistry
Distinguish between primary and secondary cells with one example each.
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Chemical Kinetics
Define the rate of a chemical reaction. Distinguish between average and instantaneous rate.
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Chemical Kinetics
State the factors that affect the rate of a chemical reaction.
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Chemical Kinetics
The rate constant of a first order reaction is 6.93 x 10^-3 s^-1. Calculate its half-life.
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Chemical Kinetics
Write the Arrhenius equation and define activation energy.
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Chemical Kinetics
How does a catalyst increase the rate of a reaction?
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Chemical Kinetics
Write the units of the rate constant for a zero order and a first order reaction.
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The p-Block Elements
Name the elements of Group 15 and give their general valence shell electronic configuration and common oxidation states.
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The p-Block Elements
Why does ammonia act as a Lewis base and have a higher boiling point than phosphine (PH3)?
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