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ChemistryClass 122 marksmedium
The p-Block Elements
Describe the Ostwald process for the manufacture of nitric acid.
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Nitric acid is manufactured by the Ostwald process, which uses ammonia as the starting material. The steps are: (1) catalytic oxidation of ammonia, 4NH3 + 5O2 -> 4NO + 6H2O, using a platinum-rhodium catalyst at about 500 K; (2) oxidation of nitric oxide, 2NO + O2 -> 2NO2; and (3) absorption of nitrogen dioxide in water, 3NO2 + H2O -> 2HNO3 + NO, where the NO produced is recycled. The dilute acid is then concentrated by distillation.
3NO2 + H2O -> 2HNO3 + NO
Marking-scheme points
- ✓4NH3 + 5O2 -> 4NO + 6H2O (Pt-Rh catalyst)
- ✓2NO + O2 -> 2NO2
- ✓3NO2 + H2O -> 2HNO3 + NO
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The p-Block Elements
Distinguish between white phosphorus and red phosphorus.
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White phosphorus consists of discrete tetrahedral P4 molecules; it is soft, poisonous, very reactive, glows in the dark (chemiluminescence), catches fire in air spontaneously and is stored under water. Red phosphorus has a polymeric chain structure of linked P4 units; it is comparatively hard, non-poisonous, much less reactive, does not glow in the dark and does not catch fire spontaneously. Red phosphorus is more stable than white phosphorus.
Marking-scheme points
- ✓White P: discrete P4 molecules, poisonous, very reactive, glows, stored under water
- ✓Red P: polymeric, non-poisonous, less reactive, stable
- ✓White P is converted to red P on heating in the absence of air
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The p-Block Elements
How is ozone prepared? Why does it act as a powerful oxidising agent?
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Ozone (O3) is prepared by passing a silent electric discharge through pure, dry oxygen: 3O2 -> 2O3 (the reaction is endothermic). Ozone acts as a powerful oxidising agent because it is unstable and readily decomposes to give nascent oxygen: O3 -> O2 + [O]. This nascent oxygen is very reactive and readily oxidises other substances (for example, it turns moist starch-iodide paper blue by liberating iodine).
3O2 -> 2O3; O3 -> O2 + [O]
Marking-scheme points
- ✓Silent electric discharge through dry O2: 3O2 -> 2O3
- ✓Ozone is unstable and gives nascent oxygen: O3 -> O2 + [O]
- ✓Nascent oxygen makes it a strong oxidising agent
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The p-Block Elements
Why is fluorine the strongest oxidising agent among the halogens, and why does chlorine act as a bleaching agent?
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The p-Block Elements
Why are noble gases chemically inert? Name two compounds of xenon.
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The d- and f-Block Elements
What are transition elements? Why are they called so?
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The d- and f-Block Elements
Why do transition elements show variable oxidation states?
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The d- and f-Block Elements
Why are most transition metal compounds coloured?
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The d- and f-Block Elements
Why do transition metals and their compounds act as good catalysts?
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The d- and f-Block Elements
Write the oxidising action of potassium dichromate in acidic medium. What happens to the colour of the solution?
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The d- and f-Block Elements
What is lanthanoid contraction? State one of its consequences.
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The d- and f-Block Elements
Why do transition metals have high melting points, and why are many of their compounds paramagnetic?
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Coordination Compounds
Distinguish between the primary and secondary valency of a metal in Werner's theory.
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Coordination Compounds
Define ligand and coordination number.
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Coordination Compounds
What is a chelate ligand and an ambidentate ligand? Give one example of each.
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Coordination Compounds
What is the spectrochemical series? Distinguish between strong field and weak field ligands.
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Coordination Compounds
State any four applications of coordination compounds.
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Haloalkanes and Haloarenes
Distinguish between haloalkanes and haloarenes with one example each.
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Haloalkanes and Haloarenes
Why are haloarenes less reactive than haloalkanes towards nucleophilic substitution?
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Haloalkanes and Haloarenes
What is a dehydrohalogenation (elimination) reaction of a haloalkane? State Saytzeff's rule.
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