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800 most-asked Class 11 & 12 (+1 / +2) questions across Physics, Chemistry, Maths and Biology — each with a model answer and the exact marking-scheme points examiners reward. Revise smart, walk in calm.

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ChemistryClass 122 marksmedium

The p-Block Elements

Describe the Ostwald process for the manufacture of nitric acid.

Reveal model answer + marking points▾

Nitric acid is manufactured by the Ostwald process, which uses ammonia as the starting material. The steps are: (1) catalytic oxidation of ammonia, 4NH3 + 5O2 -> 4NO + 6H2O, using a platinum-rhodium catalyst at about 500 K; (2) oxidation of nitric oxide, 2NO + O2 -> 2NO2; and (3) absorption of nitrogen dioxide in water, 3NO2 + H2O -> 2HNO3 + NO, where the NO produced is recycled. The dilute acid is then concentrated by distillation.

3NO2 + H2O -> 2HNO3 + NO

Marking-scheme points

  • ✓4NH3 + 5O2 -> 4NO + 6H2O (Pt-Rh catalyst)
  • ✓2NO + O2 -> 2NO2
  • ✓3NO2 + H2O -> 2HNO3 + NO
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ChemistryClass 122 marksmedium

The p-Block Elements

Distinguish between white phosphorus and red phosphorus.

Reveal model answer + marking points▾

White phosphorus consists of discrete tetrahedral P4 molecules; it is soft, poisonous, very reactive, glows in the dark (chemiluminescence), catches fire in air spontaneously and is stored under water. Red phosphorus has a polymeric chain structure of linked P4 units; it is comparatively hard, non-poisonous, much less reactive, does not glow in the dark and does not catch fire spontaneously. Red phosphorus is more stable than white phosphorus.

Marking-scheme points

  • ✓White P: discrete P4 molecules, poisonous, very reactive, glows, stored under water
  • ✓Red P: polymeric, non-poisonous, less reactive, stable
  • ✓White P is converted to red P on heating in the absence of air
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ChemistryClass 122 marksmedium

The p-Block Elements

How is ozone prepared? Why does it act as a powerful oxidising agent?

Reveal model answer + marking points▾

Ozone (O3) is prepared by passing a silent electric discharge through pure, dry oxygen: 3O2 -> 2O3 (the reaction is endothermic). Ozone acts as a powerful oxidising agent because it is unstable and readily decomposes to give nascent oxygen: O3 -> O2 + [O]. This nascent oxygen is very reactive and readily oxidises other substances (for example, it turns moist starch-iodide paper blue by liberating iodine).

3O2 -> 2O3; O3 -> O2 + [O]

Marking-scheme points

  • ✓Silent electric discharge through dry O2: 3O2 -> 2O3
  • ✓Ozone is unstable and gives nascent oxygen: O3 -> O2 + [O]
  • ✓Nascent oxygen makes it a strong oxidising agent
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