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800 most-asked Class 11 & 12 (+1 / +2) questions across Physics, Chemistry, Maths and Biology — each with a model answer and the exact marking-scheme points examiners reward. Revise smart, walk in calm.

800 board questions•Model answers•Marking-scheme points•Every chapter•CBSE · ISC · State boards

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ChemistryClass 122 marksmedium

Amines

Why is aniline less basic than ethylamine (or ammonia)?

Reveal model answer + marking points▾

Aniline is less basic than ethylamine (and than ammonia) because in aniline the lone pair of electrons on the nitrogen atom is delocalised (drawn) into the benzene ring by resonance. As a result the lone pair is less available for donation to a proton, so aniline accepts a proton less readily and is a weaker base. In ethylamine, the alkyl group has an electron-releasing (+I) effect that increases the electron density on nitrogen and makes the lone pair more available, so it is more basic.

Marking-scheme points

  • ✓In aniline the N lone pair is delocalised into the ring (resonance)
  • ✓Lone pair is less available for protonation -> weaker base
  • ✓In ethylamine, +I effect of the alkyl group makes N more basic
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ChemistryClass 122 marksmedium

Amines

What is the coupling reaction of diazonium salts? Give one example.

Reveal model answer + marking points▾

The coupling reaction is a reaction in which a diazonium salt reacts with an electron-rich aromatic compound such as phenol or an aromatic amine to form a brightly coloured azo compound (containing the -N=N- linkage). For example, benzenediazonium chloride reacts with phenol in a mildly alkaline medium to give p-hydroxyazobenzene (an orange dye). These coupling reactions are used to prepare a large number of azo dyes.

Marking-scheme points

  • ✓Diazonium salt + phenol/aromatic amine -> coloured azo compound (-N=N-)
  • ✓Example: benzenediazonium chloride + phenol -> p-hydroxyazobenzene
  • ✓Used to make azo dyes
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ChemistryClass 122 markseasy

Biomolecules

Classify carbohydrates into three types based on hydrolysis, with one example of each.

Reveal model answer + marking points▾

Based on their behaviour on hydrolysis, carbohydrates are classified as: (1) monosaccharides - simple sugars that cannot be hydrolysed further into smaller units (e.g. glucose, fructose); (2) oligosaccharides - which give 2 to 10 monosaccharide units on hydrolysis, the most common being disaccharides (e.g. sucrose, which gives glucose and fructose, and maltose); and (3) polysaccharides - which give a large number of monosaccharide units on hydrolysis (e.g. starch, cellulose and glycogen).

Marking-scheme points

  • ✓Monosaccharides: cannot be hydrolysed further (glucose, fructose)
  • ✓Oligosaccharides (disaccharides): give 2-10 units (sucrose, maltose)
  • ✓Polysaccharides: give many units (starch, cellulose)
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